Sounds like you want to setup a zpool with raidz / mirroring correct? If
so during the installation you are given the option to add additional
disks to a new ZFS pool, and you can select their type as well,
raidz/mirror. If you want to setup some data partition post-install this
way then you'll probably want to take a look at the "zpool" command, and
maybe the tutorial:
http://wiki.freebsd.org/ZFSQuickStartGuide